N,N-Bis(2-bromoethyl)aniline
نویسندگان
چکیده
The mol-ecule of the title compound, C(10)H(13)Br(2)N, has a twofold rotation axis along the N-C(phen-yl) bond. The compound shows a slightly distorted trigonal planar geometry around the N atom. The structural study shows the presence of inter-molecular C-H⋯Br inter-actions, resulting in a three-dimensional supra-molecular architecture.
منابع مشابه
Syntheses, structures, and properties of copper(II) complexes of bis(2-pyridylmethyl) derivatives of o-, m-, and p-phenylenediamine and aniline.
Copper(II) complexes of the ligand 1,n-bis[bis(2-pyridylmethyl)amino]benzene with n = 2-4 (1,n-tpbd) and its mononuclear derivative bis(2-pyridylmethyl)aniline (phbpa) were synthesized and structurally characterized. Magnetic measurements and DFT calculations were performed on [CuCl2(phbpa)], [Cu2Cl4(1,3-tpbd)], [(Cu2Cl2(ClO4)(1,3-tpbd))Cl(Cu2Cl2(OH2)(1,3-tpbd))](ClO4)2, and [Cu2(OH2)2(S2O6)(1,...
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متن کاملN-[Bis(4-fluorophenyl)methylene]aniline
The title compound, C(19)H(13)F(2)N, was synthesized by an addition reaction of bis-(4-fluoro-phen-yl)methanone with aniline. The dihedral angles formed by the fluoro-benzene rings with the aniline ring are 81.04 (5) and 64.15 (5)°. In the crystal packing, inter-molecular C-H⋯F hydrogen bonds link mol-ecules into zigzag chains parallel to the c axis.
متن کامل3,5-Dinitrobenzyl methanesulfonate
The title compound, C(8)H(8)N(2)O(7)S, an inter-mediate in the synthesis of N,N-bis-(2-hydroxy-ethyl)-3,5-dinitro-aniline, exists as a discrete mol-ecule; the nitro groups are twisted with respect to the aromatic system [dihedral angles = 17.0 (1) and 26.3 (1)°].
متن کامل{N,N-Bis[2-(diphenylphosphanyl)ethyl]aniline}(η2-dibenzylideneacetone)palladium(0)
In the title complex, [Pd(C(34)H(33)NP(2))(C(17)H(14)O)], the Pd(0) atom is coordinated in a trigonal planar geometry formed by two P atoms of a bis-[(diphenyl-phosphino)eth-yl]aniline ligand and a C=C (η(2)) bond involving the C atoms that are in the α,β positions relative to the central ketone of the dibenzyl-ideneacetone ligand.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007